Towards Ion-Selective Membranes with Electrogenerated Chemiluminescence Detection: Visualizing Selective Ru(bpy)32+ Transport Across a Plasticized Poly(vinyl chloride) Membrane
Gastón A. Crespo
Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, Quai E.-Ansermet 30, CH-1211 Geneva, Switzerland
Search for more papers by this authorGünter Mistlberger
Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, Quai E.-Ansermet 30, CH-1211 Geneva, Switzerland
Search for more papers by this authorCorresponding Author
Eric Bakker
Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, Quai E.-Ansermet 30, CH-1211 Geneva, Switzerland
Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, Quai E.-Ansermet 30, CH-1211 Geneva, SwitzerlandSearch for more papers by this authorGastón A. Crespo
Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, Quai E.-Ansermet 30, CH-1211 Geneva, Switzerland
Search for more papers by this authorGünter Mistlberger
Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, Quai E.-Ansermet 30, CH-1211 Geneva, Switzerland
Search for more papers by this authorCorresponding Author
Eric Bakker
Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, Quai E.-Ansermet 30, CH-1211 Geneva, Switzerland
Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, Quai E.-Ansermet 30, CH-1211 Geneva, SwitzerlandSearch for more papers by this authorAbstract
We report here on an attractive concept to integrate electrochemically triggered ion-selective transport across an ion-selective plasticized PVC membrane and electrogenerated chemiluminescence (ECL) as a detection technique. This will eventually form the basis for an alternate transduction mechanism for electrochemical ion sensors. To this end, the selective extraction of the ECL reagent Ru(bpy)32+ is demonstrated by an o-NPOE plasticized PVC membrane doped with lipophilic cation-exchanger. Chemical imaging of Ru(bpy)32+ electrotransported across the PVC membrane demonstrates the feasibility of this concept as a future trend for two dimensional ion sensing.
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